GHS危險(xiǎn)說明和防護(hù)代碼

Physical Hazards物理性危害

H200	Unstable explosives.
H201	Explosive; mass explosion hazard.
H202	Explosive, severe projection hazard.
H203	Explosive; fire, blast or projection hazard.
H204	Fire or projection hazard.
H205	May mass explode in fire.
H206	Fire, blast or projection hazard; increased risk of explosion if desensitizing agent is reduced.
H207	Fire or projection hazard; increased risk of explosion if desensitizing agent is reduced.
H208	Fire hazard; increased risk of explosion if desensitizing agent is reduced.
H220	Extremely flammable gas.
H221	Flammable gas.
H222	Extremely flammable aerosol.
H223	Flammable aerosol.
H224	Extremely flammable liquid and vapour.
H225	Highly flammable liquid and vapour.
H226	Flammable liquid and vapour.
H227	Combustible liquid.
H228	Flammable solid.
H229	Pressurised container: may burst if heated.
H230	May react explosively even in the absence of air.
H231	May react explosively even in the absence of air at elevated pressure and/or temperature.
H232	May ignite spontaneously if exposed to air.
H240	Heating may cause an explosion.
H241	Heating may cause a fire or explosion.
H242	Heating may cause a fire.
H250	Catches fire spontaneously if exposed to air.
H251	Self-heating: may catch fire.
H252	Self-heating in large quantities; may catch fire.
H260	In contact with water releases flammable gases which may ignite spontaneously.
H261	In contact with water releases flammable gases.
H270	May cause or intensify fire; oxidizer.
H271	May cause fire or explosion; strong oxidizer.
H272	May intensify fire; oxidizer.
H280	Contains gas under pressure; may explode if heated.
H281	Contains refrigerated gas; may cause cryogenic burns or injury.
H290	May be corrosive to metals.

Health Hazards健康危險(xiǎn)性

H300	Fatal if swallowed.
H300 + H310	Fatal if swallowed or in contact with skin.
H300 + H310 + H330	Fatal if swallowed, in contact with skin or if inhaled.
H300 + H330	Fatal if swallowed or if inhaled.
H301	Toxic if swallowed.
H301 + H311	Toxic if swallowed or in contact with skin.
H301 + H311 + H331	Toxic if swallowed, in contact with skin or if inhaled.
H301 + H331	Toxic if swallowed or if inhaled.
H302	Harmful if swallowed.
H302 + H312	Harmful if swallowed or in contact with skin.
H302 + H312 + H332	Harmful if swallowed, in contact with skin or if inhaled.
H302 + H332	Harmful if swallowed or if inhaled.
H303	May be harmful if swallowed.
H303 + H313	May be harmful if swallowed or in contact with skin.
H303 + H313 + H333	May be harmful if swallowed, in contact with skin or if inhaled.
H303 + H333	May be harmful if swallowed or if inhaled.
H304	May be fatal if swallowed and enters airways.
H305	May be harmful if swallowed and enters airways.
H310	Fatal in contact with skin.
H310 + H330	Fatal in contact with skin or if inhaled.
H311	Toxic in contact with skin.
H311 + H331	Toxic in contact with skin or if inhaled.
H312	Harmful in contact with skin.
H312 + H332	Harmful in contact with skin or if inhaled.
H313	May be harmful in contact with skin.
H313 + H333	May be harmful in contact with skin or if inhaled.
H314	Causes severe skin burns and eye damage.
H315	Causes skin irritation.
H315 + H320	Causes skin and eye irritation.
H316	Causes mild skin irritation.
H317	May cause an allergic skin reaction.
H318	Causes serious eye damage.
H319	Causes serious eye irritation.
H320	Causes eye irritation.
H330	Fatal if inhaled.
H331	Toxic if inhaled.
H332	Harmful if inhaled.
H333	May be harmful if inhaled.
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335	May cause respiratory irritation.
H336	May cause drowsiness or dizziness.
H340	May cause genetic defects.
H341	Suspected of causing genetic defects.
H350	May cause cancer.
H350i*	May cause cancer by inhalation.
H351	Suspected of causing cancer.
H360	May damage fertility or the unborn child.
H360D*	May damage the unborn child.
H360Df*	May damage the unborn child. Suspected of damaging fertility.
H360F*	May damage fertility.
H360FD*	May damage fertility. May damage the unborn child.
H360Fd*	May damage fertility. Suspected of damaging the unborn child.
H361	Suspected of damaging fertility or the unborn child.
H361d*	Suspected of damaging the unborn child.
H361f*	Suspected of damaging fertility.
H361fd*	Suspected of damaging fertility. Suspected of damaging the unborn child.
H362	May cause harm to breast-fed children.
H370	Causes damage to organs.
H371	May cause damage to organs.
H372	Causes damage to organs through prolonged or repeated exposure.
H373	May cause damage to organs through prolonged or repeated exposure.

Environmental Hazards環(huán)境危害

H400	Very toxic to aquatic life.
H401	Toxic to aquatic life.
H402	Harmful to aquatic life.
H410	Very toxic to aquatic life with long lasting effects.
H411	Toxic to aquatic life with long lasting effects.
H412	Harmful to aquatic life with long lasting effects.
H413	May cause long lasting harmful effects to aquatic life.
H420	Harms public health and the environment by destroying ozone in the upper atmospere.

European Union Hazard Statements歐盟危險(xiǎn)聲明：

EUH001	Explosive when dry.
EUH014	Reacts violently with water.
EUH018	In use may form flammable/explosive vapour-air mixture.
EUH019	May form explosive peroxides.
EUH029	Contact with water liberates toxic gas.
EUH031	Contact with acids liberates toxic gas.
EUH032	Contact with acids liberates very toxic gas.
EUH044	Risk of explosion if heated under confinement.
EUH066	Repeated exposure may cause skin dryness or cracking.
EUH070	Toxic by eye contact.
EUH071	Corrosive to the respiratory tract.
EUH201	Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
EUH201A	Warning! Contains lead.
EUH202	Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children.
EUH203	Contains chromium (VI). May produce an allergic reaction.
EUH204	Contains isocyanates. May produce an allergic reaction.
EUH205	Contains epoxy constituents. May produce an allergic reaction.
EUH206	Warning! Do not use together with other products. May release dangerous gases (chlorine).
EUH207	Warning! Contains cadmium. Dangerous fumes are formed during use. See information supplied by the manufacturer. Comply with the safety instructions.
EUH208	Contains (name of sensitising substance). May produce an allergic reaction.
EUH209	Can become highly flammable in use.
EUH209A	Can become flammable in use.
EUH210	Safety data sheet available on request.
EUH401	To avoid risks to human health and the environment, comply with the instructions for use.

Precautionary Statements

安全防護(hù)聲明

P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P244 Keep valves and fittings free from oil and grease.
P250 Do not subject to grinding/shock/friction/....
P251 Do not pierce or burn, even after use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P263 Avoid contact during pregnancy and while nursing.
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P272 Contaminated work clothing should not be allowed out of the workplace.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P282 Wear cold insulating gloves and either face shield or eye protection.
P283 Wear fire resistant or flame retardant clothing.
P284 [In case of inadequate ventilation] wear respiratory protection.

Precautionary statements - Response 防護(hù)聲明

P301 IF SWALLOWED:
P302 IF ON SKIN:
P303 IF ON SKIN (or hair):
P304 IF INHALED:
P305 IF IN EYES:
P306 IF ON CLOTHING:
P308 IF exposed or concerned:
P310 Immediately call a POISON CENTER/doctor/...
P311 Call a POISON CENTER/doctor/...
P312 Call a POISON CENTER/doctor/.../if you feel unwell.
P313 Get medical advice/attention.
P314 Get medical advice/attention if you feel unwell.
P315 Get immediate medical advice/attention.
P320 Specific treatment is urgent (see ... on this label).
P321 Specific treatment (see ... on this label).
P330 Rinse mouth.
P331 Do NOT induce vomiting.
P332 If skin irritation occurs:
P333 If skin irritation or rash occurs:
P334 Immerse in cool water [or wrap in wet bandages].
P335 Brush off loose particles from skin.
P336 Thaw frosted parts with lukewarm water. Do not rub affected area.
P337 If eye irritation persists:
P338 Remove contact lenses, if present and easy to do. Continue rinsing.
P340 Remove person to fresh air and keep comfortable for breathing.
P341 If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342 If experiencing respiratory symptoms:
P350 Gently wash with plenty of soap and water.
P351 Rinse cautiously with water for several minutes.
P352 Wash with plenty of water/...
P353 Rinse skin with water [or shower].
P360 Take off immediately all contaminated clothing.
P361 Remove/Take off immediately all contaminated clothing.
P362 Take off contaminated clothing.
P363 Wash contaminated clothing before reuse.
P364 And wash it before reuse.
P370 In case of fire:
P371 In case of major fire and large quantities:
P372 Explosion risk.
P373 DO NOT fight fire when fire reaches explosives.
P375 Fight fire remotely due to the risk of explosion.
P376 Stop leak if safe to do so.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378 Use ... to extinguish.
P380 Evacuate area.
P381 In case of leakage, eliminate all ignition sources.
P390 Absorb spillage to prevent material damage.
P391 Collect spillage.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/....
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/... IF you feel unwell.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302+P334 IF ON SKIN: Immerse in cool water or wrap in wet bandages.
P302 +P335 +P334 IF ON SKIN: Brush off loose particles from skin. Immerse in cool water or wrap in wet bandages.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P304+P312 IF INHALED: Call a POISON CENTER or doctor/... if you feel unwell.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306+P360 IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P308+P311 IF exposed or concerned: Call a POISON CENTER/doctor/...
P308+P313 IF exposed or concerned: Get medical advice/attention.
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P336 + P315 Thaw frosted parts with lukewarm water. Do not rub affected area. Get immediate medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/attention.
P342+P311 If experiencing respiratory symptoms: Call a POISON CENTER/ doctor/...
P361 + P364 Take off immediately all contaminated clothing and wash it before reuse.
P362 + P364 Take off contaminated clothing and wash it before reuse.
P370 +P372 +P380 +P373 In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives.
P370+P376 In case of fire: Stop leak if safe to do so.
P370+P378 In case of fire: Use ... to extinguish.
P370+P380+P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P370 +P380 +P375 +P378 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use ... to extinguish.]
P371+P380+P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.

Precautionary statements — Storage

P401 Store in accordance with ...
P402 Store in a dry place.
P403 Store in a well-ventilated place.
P404 Store in a closed container.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P405 Store locked up.
P406 Store in corrosive resistant/ ... container with aresistant inner liner.
P407 Maintain air gap between stacks or pallets.
P410 Protect from sunlight.
P411 Store at temperatures not exceeding ... °C/ ... °F.
P412 Do not expose to temperatures exceeding 50 °C/ 122 °F.
P413 Store bulk masses greater than ... kg/ ... lbs at temperatures not exceeding ... °C/ ... °F.
P420 Store separately.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.

Precautionary statements — Disposal預(yù)防聲明

P501 Dispose of contents/container to..…
P502 Refer to manufacturer or supplier for informationon on recovery or recycling.
P503 Refer to manufacturer/supplier…for information on disposal/ recovery/recycling.

PICTOGRAMS AND HAZARD CODES

危險(xiǎn)告知圖及安全代碼

Compared to the current EU system the most noticeable change are the pictograms (formerly: hazard symbols). While the most of the GHS pictograms
have an equivalent in the old system, the pictograms GHS 04, GHS 07 and GHS 08 are completely new.

The GHS System is built on 16 physical, 10 health and 3 environmental hazard classes and comprises the following communication elements:

9 Pictograms 9張危險(xiǎn)性告知圖

Description	Pictogram	Hazard class and hazard category:
Exploding Bomb GHS01		Unstable explosives Explosives of Divisions 1.1, 1.2, 1.3, 1.4 Self reactive substances and mixtures, Types A,B Organic peroxides, Types A,B
Flame GHS02		Flammable gases, category 1 Flammable aerosols, categories 1,2 Flammable liquids, categories 1,2,3 Flammable solids, categories 1,2 Self-reactive substances and mixtures, Types B,C,D,E,F Pyrophoric liquids, category 1 Pyrophoric solids, category 1 Self-heating substances and mixtures, categories 1,2 Substances and mixtures, which in contact with water, emit flammable gases, categories 1,2,3 Organic peroxides, Types B,C,D,E,F
Flame Over Circle GHS03		Oxidizing gases, category 1 Oxidizing liquids, categories 1,2,3
Gas Cylinder GHS04		Gases under pressure: - Compressed gases - Liquefied gases - Refrigerated liquefied gases - Dissolved gases
Corrosion GHS05		Corrosive to metals, category 1 Skin corrosion, categories 1A,1B,1C Serious eye damage, category 1
Skull and Crossbones GHS06		Acute toxicity (oral, dermal, inhalation), categories 1,2,3
Exclamation Mark GHS07		Acute toxicity (oral, dermal, inhalation), category 4 Skin irritation, category 2 Eye irritation, category 2 Skin sensitisation, category 1 Specific Target Organ Toxicity – Single exposure, category 3
Health Hazard GHS08		Respiratory sensitization, category 1 Germ cell mutagenicity, categories 1A,1B,2 Carcinogenicity, categories 1A,1B,2 Reproductive toxicity, categories 1A,1B,2 Specific Target Organ Toxicity – Single exposure, categories 1,2 Specific Target Organ Toxicity – Repeated exposure, categories 1,2 Aspiration Hazard, category 1
Environment GHS09		Hazardous to the aquatic environment - Acute hazard, category1 - Chronic hazard, categories 1,2